With some kinds of activities, if you get it wrong the first time, you can do it over. Working around power lines is not one of those activities. If your safety practices are anything but flawless, your risk of electrocution is high.
One key to success here is to have the right attitude. Simply using the personal protective equipment (PPE) your employer “makes” you use does not protect you. Even if you use it correctly, for example rolling up your gloves to test them rather than blowing into them to test them, PPE is not your primary defense against power line hazards.
PPE is that final layer of protection after you’ve executed all the other safety procedures and are still being mindful of hazards while working. For example, you perform lockout/tagout on a power cable. Maybe it has damaged insulation or is backfed. Use a meter to verify the cable has been de-energized, and then apply safety grounds to ensure it stays de-energized.